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The problem of the formation of volatile organochlorine compounds during the initial distillation of oil as a result of decomposition of chemicals containing salts of quaternary ammonium compounds

https://doi.org/10.24887/2587-7399-2019-4-63-69

Abstract

Research, the results of which are presented in the article, are devoted to the detection of LHOS in naphtha and chemical reagents and are due to stricter requirements for the quality of marketable oil in accordance with the Technical Regulation of the Eurasian Economic Union On the Safety of Oil Prepared for Transportation and (or) TR EAEU 045/2017. The practical significance of the work is to reduce the risk of the formation of volatile organochlorine compounds in marketable oil due to the use of chemicals. As a result of the studies, the formation of volatile organochlorine compounds (the so-called secondary organochlorine compounds) was discovered due to the decomposition of salts of Quaternary ammonium bases contained in some oilfield chemicals.

About the Authors

A. V. Sinev
Gazpromneft-Prirazlomnoe LLC
Russian Federation

Saint-Petersburg



T. V. Devyashin
Gazpromneft-Prirazlomnoe LLC
Russian Federation

Saint-Petersburg



A. M. Kunakova
Gazpromneft NTC LLC
Russian Federation

Saint-Petersburg



L. R. Sayfutdinova
Gazpromneft NTC LLC
Russian Federation

Saint-Petersburg



F. G. Usmanova
Gazpromneft NTC LLC
Russian Federation

Saint-Petersburg



A. N. Krikun
NDCS Neftepromсhim
Russian Federation

Kazan



A. E. Lestev
NDCS Neftepromсhim
Russian Federation

Kazan



References

1. Krikun N.G., Lost control. Problems of chemical products in the Russian oil industry (In Russ.), TekhNADZOR, 2012, no. 8(69), pp. 40–41.

2. Okhlopkov A.S., Svoystva tovarnoy syroy nefti, pozvolyayushchie identifitsirovat' istochnik neftyanogo zagryazneniya okruzhayushchey prirodnoy sredy (Properties of commercial crude oil, allowing to identify the source of oil pollution of the environment): thesis of candidate of chemical science, Nizhniy Novgorod, 2015.

3. ASTM D4929, Standard test method for determination of organic chloride content in crude oil.

4. Ugryumov O.V., Ivshin Ya.V., Azotfosforsoderzhashchie ingibitory korrozii neftepromyslovogo oborudovaniya (Nitrogen phosphorus inhibitors of oilfield equipment corrosion), Kazan': Publ. of KSU, 2009, 213 p.


Review

For citations:


Sinev A.V., Devyashin T.V., Kunakova A.M., Sayfutdinova L.R., Usmanova F.G., Krikun A.N., Lestev A.E. The problem of the formation of volatile organochlorine compounds during the initial distillation of oil as a result of decomposition of chemicals containing salts of quaternary ammonium compounds. PROneft. Professionally about Oil. 2019;(4):63-69. (In Russ.) https://doi.org/10.24887/2587-7399-2019-4-63-69

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ISSN 2587-7399 (Print)
ISSN 2588-0055 (Online)